The formulas to find the phase matching angle of a biaxial crystal system is only available, if the refractive index is n1>n2>n3 or n3>n2>n1. But how to find the optic axis for biaxial crystal, if the refractive index of the crystal is n2>n3>n1?
You don’t explain the method of preparation u sample? you have first, for example substrate , coated with….. ? then you coated again with other material ….? Finally you three layers. Can give more information