I have isolated group of secondary metabolites that is mostly group of antimycin A family. But I do not have a standard to compare it to. I just compared it to literature data (MS, UV-VIS). Now when I wanted to isolate them on preparative column I couldn´t detect them. Do they degrade so quickly? they were stored in the fridge. Any experience with this? Does someone have just tiny bit of standard available just to inject into HPLC for an analysis? Thank you for any comments