Are you using semiconductor NP's? If this is your case, you can use the Energy gap shifting that occurs when you reduce the size of your system. You have just to use a simple second grade equation. You can try this method
You can find these empirical fittings for CdSe, CdTe and CdS semiconductor QDs, where D (nm) is the size of a given nanocrystal sample, and lambda (nm) is the wavelength of the first excitonic peak from the absorption spectrum of the corresponding sample.