Within the following publication you will find a detailed analysis of an out-of-the-box wafer And the water contact angle. Which have a finite value, in general as nearer to zero as “newer”. Pure Si-Metall does not have an angle at all. The Si surface is also not ideal for CA measurement using water because it’s reactive towards the liquid.
For commercially available single crystalline Si(hkl) wafers, a native silicon oxide layers with thickness ~ 2-5 nm exists. The native oxide layer has hydrophilic nature. In contrary, if you remove the native oxide layer (with the help of any etchant like HF solution), the bare Si (hkl) substrate has the hydrophibic nature.
K. Hermansson, U. Lindberg, B. Hök, and G. Palmskog, Wetting properties of silicon surfaces, International Conference on Solid-State Sensors and Actuators, 1991.