Boiling point temperatures for the chloroform-methanol binary system can be obtained from Table 13-1, entitled "Constant-pressure liquid-vapor equilibrium data for selected binary systems", in: R.H. Perry, D.W. Green, J.O. Maloney (Eds.), "Perry's Chemical Engineers’ Handbook", 7th ed., McGraw-Hill, 1997.
CHCl3 build azeotrope with EtOH : https://en.wikipedia.org/wiki/Azeotrope_tables
Boiling point is 61.1oC , composition CHCl3 : EtOH = 93 : 7 (by weight). Mixture will boil at constant temperature up to full consumption of CHCl3, then vapor temperature will drop for some time, and next will rise to boiling temperature of pure EtOH.
Please note that this data are correct for pure (anhydrous) mixture; with water it can build triple azeotrope.