Generally, there will be boiling point elevation with LiBr concentration. To find particular value, you should have to go through the pressure-temperature-concentration chart or table of LiBr-H2O solution published by several authors available online.
Cf.: J. Pátek, J. Klomfar, "A computationally effective formulation of the thermodynamic properties of LiBr–H2O solutions from 273 to 500 K over full composition range", International Journal of Refrigeration, 29(4) June 2006, 566-578.Article A computationally effective formulation of the thermodynamic...