02 February 2014 2 10K Report

The article below states 'the affinity for the clay surface decreased with increasing number of ethylene oxide units'. Likely it is meant relatively to solubility in water. It further states that 'flocculation was attributed to the bridging of micelles between the particles'.

I have never heard about bridging between micelles and in particular micelles of nonionic surfactants. On contrary polyethylene glycol shells usually are associated with steric stabilization. I would explain flocculation with observed maximum at about 50 % coverage as result of shielding effective electrostatic repulsion counteracted at higher surface coverage by steric repulsion of the ethylene glycol oligomers.

Book Effect of polymers on the rheology of clay suspensions

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