Iron oxide probably wants to lose electrons so could be a good anode. But does it give an overpotential for the oxygen production? What about N doped carbon?
Hi there, losing electrons sounds like iron oxides are being oxidized, in which case you don't have a supercapacitor. As has been said, N has one lone pair and O has two which make the surface negatively charged. This is important to attract cations to the surface. Needlesstosay, the amount of charge you can get out of a capacitor depends on the ability of electrode surfaces to attract charged ions.