Hi Dears
I study on suitbale materials for Hydrogen Storage applications via severe plastic deformation method. As you know, for example Mg and Ti, which are considered as two light metals, are the 7th and 9th most abundant elements in the earth’s crust. Since both elements react with hydrogen and produce hydrides of MgH2 and TiH2 (with hydrogen contents of 7.6 and 4.0 wt.%, respectively), they are considered as candidates for hydrogen storage.
Thank you for regarding my question.
sincerely
According to IEA ( https://www.iea.org/publications/freepublications/publication/hydrogen.pdf ) there are four main groups of solid materials suitable for storage of hydrogen:
- Carbon-based materials (nanotubes and graphite nanofibers);
- Other high surface area materials: zeolites, metal oxide frameworks (MOFs) and clathrate hydrates;
- Rechargeable and complex hydrides (borohydrides, alanates and amides);
- Chemical hydrides (H2O-reactive): LiH, NaH, MgH2 , CaH2 ;
- Chemical hydrides (thermal): NH4BH4, NH3BH3, NH2BH2, NHBH ;
Hi Sina
That's quite a big question so I think you will probably need to be a bit more specific.
Florian's list above is also missing some significant classes of material, such as interstitial metal hydrides. I don't think that IEA-HIA report is the best source of information, particularly as it is now over ten years old.
You'll find some useful and more up-to-date papers in a Topical Collection on Hydrogen-based Energy Storage in Applied Physics A:
https://link.springer.com/article/10.1007/s00339-016-9652-3
That was compiled by the current IEA-HIA task on the topic...
Best regards,
Darren
Hi Sina
I should probably correct what I said before because I've realised the category 'Rechargeable and complex hydrides' includes interstitial hydrides.
Florian's list includes only complex hydrides after that category - borohydrides, alanates and amides are all complex hydrides. That was what confused me.
Table 7 in the IEA-HIA report actually lists 'Rechargeable hydrides' as one of the four categories, with that category including 'Alloys and intermetallics', 'Nanocrystalline' and 'Complex' as different types of rechargeable hydride. I think that's a bit clearer...
Best regards,
Darren
Dear Florian Glodeanu and Darren Paul Broom
thank you so much for sharing valuable information. My goal is to investigate metal materials and intermetallic compounds and severe plastic deformation applications in hydrogen storage. it is better i modify my question. Thus, which metals are appropriate for hydrogen storege in solid state?
thank you
see the following link, may be help you
http://www.sciencedirect.com/science/article/pii/S1369702103009222
Hi Sina
Andreas Züttel's article (linked to above by Rk Fakher Alfahed) is a very good starting point.
There is too much detail, really, to cover in an answer here.
I tried to give an overview of different materials and hence metals in Chapter 2 of my book, which is available as a free download from the Springer website:
http://www.springer.com/gb/book/9780857292209
Go to 'Download Sample pages 1 pdf' at the bottom or try this link:
http://www.springer.com/cda/content/document/cda_downloaddocument/9780857292209-c1.pdf?SGWID=0-0-45-1097444-p174067891
In short, most metals will absorb hydrogen but different elements do so under very different conditions. Some are very difficult to hydride, others easy, but they can be combined in different ways (as alloys and intermetallics) to make practical hydrogen storage materials; however, there are so many combinations and possibilities that the situation is difficult to summarise. Important practical considerations include cost and the molar mass of the host. Mg and Ti, as you mention in your question, are good, in principle, because they are light and absorb two hydrogen atoms for every metal, but there are other candidates too.
I hope this helps for now.
Best regards,
Darren
Dr. Darren Paul Broom and Dr. Rk Fakher Alfahed
I appreciate your kindly helps. Also, I decide to discover a new high entropy alloy for this research.
regards,
Sina Ghaemi Khiavi
Hi Sina
That sounds like an interesting idea. It seems that hydrogen storage in CoFeMnTiVZr, ZrTiVCrFeNi and TiZrNbMoV alloys has been investigated:
http://www.sciencedirect.com/science/article/pii/S0360319910011882
http://www.sciencedirect.com/science/article/pii/S0360319913012676
http://www.sciencedirect.com/science/article/pii/S0360319914004273
And here's another example:
https://www.nature.com/articles/srep36770
Maybe there are many more waiting to be discovered. Good luck!
Best regards,
Darren
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