I would like to know what type of interactions exist if I dissolve PLA in dichloromethane.. I guess they're hydrophobic interactions. PLease, I need some article that talk about ir.
As PLA is not soluble in water, you can hear about "hydrophobic" interactions in several discussions. It is more informative to have a look at Hansen solubility parameters. For details see: Hansen, Charles (2007). Hansen Solubility Parameters: A user's handbook, Second Edition. Boca Raton, Fla: CRC Press. Values you can find in: Rafael Auras, Loong-Tak Lim, Susan E. M. Selke, Hideto Tsuji, Poly(Lactic Acid): Synthesis, Structures, Properties, Processing, and Applications, Wiley, 2010, pp.84-87. Hansen solubility parameters show contributions for disperse interaction, but also remarkable contributions from polar and hydrogen bonding terms in your case (PLA and dichloromethane).