Sediments derived from granite would contain Zircon, Tourmalin and Rutile heavy minerals. Quaternary sediments also would have stable and unstable heavy minerals 

Zircon, tourmaline, rutile, epidote, pyroxene, amphibole

weathered will yield spinel, magnetite, hematite, apatite, baryte, Monzonite, REE bearing minerals prochlorite etc...

Dear Mussa,

I know Malawi though my various assignments to the Geological Survey and I would like to focus only on some HM mineral/ HM associations.

(1) biotite gneiss..is similar to your  second group but hard to specify

(2) Sn, W,  U,  Be

(3) REE, Coltan

(4) Ti, REE, Fe oxides, Fe-Cr  spinel, Coltan, Zr, corundum with HM chromophores

Best regards

H.G.Dill

Thank you very much Dill, the papers have helped alot.

Fe, Cu, Zn, Mn and Cr are the dominant heavy metals.

Thank you Mitra, could you please highlight the link between these metals and the geology I have described. These are the metals I am interested in.

Arsenic may be found in the igneous rocks 

Here are to URL's that provide papers that may be of interest

www.sciencedirect.com/science/article/pii/S0191814199000528

link.springer.com/article/10.1007/s10661-012-2806-7/fulltext.htmu

HI,

Fe,Ca CO3,Pb,Te   C,Mg,Sn,As,W

Thank you so much for the answers,  they have helped alot

Arsenic being associated with Mn & Fe concentration of them is matter of interest

Arsenic is more often associated to copper, particularly in sulfide ore formations.

Regards

I agree with you Sumanth Chinthala