I'm doing non-linear least squares iftting of TCSPC data and my residuals don't trend with my chi-squared values. IE a fit with unstructured residuals will have a chi-squared of ~0.54, but a fit with some remaining structure in the residuals will have a chi-squared ~0.96.

I would have expected their goodness or badness to vary together, but that doesn't seem to be the case. Which is generally most trustworthy? 

I'm using the FluoFit software,for reference.

Thanks very much.

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