to obtain a better photocatalysis activity, does titanium dioxide need to be only anatase or a combination of anatase and rutile phases (my synthesis is anatase %77 and rutile %23)
Both of them have good photo-catalytic activity. However, antase is known to be more efficiently separate photo-excited charge carriers than rutile. I recommend the following article for you to read
Article Enhancing the Photocatalytic Activity of TiO2 Catalysts
Besides, a mix between antase & rutile is commercially known as Degussa P25 and many references mentioned that it has a greater photo-catalytic activity and currently there is so many articles investigate in enhancing the photo-catalytic activity of TiO2.
Finally, for sure that the photo-catalytic activity of any semiconductor may be affected by several factors, so it may depend on your purpose of using TiO2.