Reham Dabboura It is important to use correct terminology in any scientific discourse. People may get the wrong impression of you if you're using terms such as tio2 (rather than TiO2) and PH (rather than pH). Search the literature (including Research Gate) for recipes for your application.
I suggest searching the literature in order to know more about the influence of the pH on the sol-gel process of these nanoparticles. Nevertheless, regarding SiO2 nanoparticles, usually pH below 7 tend to form poorly crosslinked gels while pH above 7 tend to form nanoparticles. A lot of articles show the dependance of the size of the nanoparticles and the pH and recipes employed.
It depends on the size of the nanoparticles you want. An acid pH provides smaller sizes than a basic pH. Something similar with coatings, but a greater width carries a greater risk of cracking. I think an acid pH (2.00-4.00) is better in your case in coatings.