I obtained the thin film using spin-coating method by using sparingly soluble solvents like( THF, DMF) having the rpm 1500 for 60 sec.
Generally, the shift of the peaks in XRD can be attributed to:
1- The change of the d-spacing of the investigated system, this may attributed to many reasons including the effect of dopant, strain, surface (for nanomaterials
How the effect of the dopant and strain attributed to change of d spacing in the investigated system?
Please refer to any textbook on XRD, Elements of X-Ray Diffraction by Cullity, B. D is a good one.
Also, you can find details on previous RG answers:
https://www.researchgate.net/post/Any_suggestions_for_why_the_XRD_peak_shifts
https://www.researchgate.net/post/When_XRD_analyzed_what_does_it_mean_when_a_shifted_peak_is_either_left_hand_or_right_hand2
https://www.researchgate.net/post/What_is_the_reason_of_peak_shifting_in_XRD_towards_higher_angle_side_after_the_sample_has_been_irradiated
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