in xps their may be shift of binding energy and increasing or decreasing its intensity
Rules of thumb:
-higher binding energy partial charge shifted in positive direction
-higher intensity higher stoichiometric coefficients
For element-specific exceptions, check out
https://www.thermofisher.com/de/de/home/materials-science/learning-center/surface-analysis.html
And also, please read an actual introduction to XPS, these aspects were the most basic things one needs to know about this method.
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