grain = one crystal !!! Orientation of grains may be same or may not be same. But two different orientation leads to mismatch resulting in high energy state called grain boundary.
Thank you so much in advance. I think that, we can define a grain as single crystal with highly condensed element within its boundary, or it is a small container of one chemical element! for example in Ferite, the grain is a condense of Carbon element with specified boundary. For more detail, please see the famous engineering book ASHBY, you will rich information. See the attachment, please give me feedback.