i guess TPD is used to know the the active side of catalyst
CO as a weak Lewis base helps to determine acid sites catalysts.
CO TPD profiles gives information about adsorption behavior of the CO gas with surface.
1) As we know Chemisorption follows monolayer adsorption amount of CO gas adsorbed is proportional to the active surface area of the catalyst.
so we can say
Peak area~Amount of CO~ active surface area.
2) Also temperature of desorption shows the strength of CO chemisorption (CO bond with metal surface).
3) Different desorption peaks indicate different binding modes.
Kindly search in research papers how this is useful and interpreted.
How can calculate the active sites of a heterogeneous catalyst using CO-TPD results? is there any specific formula?
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