i am working on aqueous base DSSC and facing the dye desorption issue from the photoanode when interact with water, i want to know some techniques to reduced dye desorption.
Dear Muhammad Sadiq , you may want to refer to the following: https://purehost.bath.ac.uk/ws/portalfiles/portal/187920954/Thomas_Risbridger_PhD_Thesis.pdf
Dye desorption is a common issue in DSSCs that can lead to a decrease in the overall performance of the device. There are a few different techniques that can be used to reduce dye desorption in aqueous-based DSSCs:
Surface modification: The photoanode can be modified to improve the stability of the dye. This can be done by incorporating a layer of hydrophobic or hydrophilic molecules on the surface of the photoanode to increase the strength of the dye-adsorbent interaction.
Use of a cross-linker: A cross-linker can be used to chemically link the dye molecules to the surface of the photoanode, which will help to prevent desorption.
Use of a thicker electrolyte film: A thicker electrolyte film can be used to reduce the rate of dye desorption. This can be achieved by using a thicker layer of electrolyte or by using an electrolyte with a higher viscosity.
Use of a co-adsorbent: A co-adsorbent can be used to improve the stability of the dye. This can be done by adding a small amount of a second molecule that can bind to the dye and prevent it from desorbing.
Use of a protective coating: A protective coating can be applied over the dye to reduce the rate of desorption. This can be done by using polymers, waxes or other materials that can form a physical barrier to protect the dye from desorption.
It's worth noting that in order to effectively reduce dye desorption it may be necessary to use a combination of these techniques. Additionally, it's important to keep in mind that each DSSC system is unique and the most effective technique(s) will depend on the specific system being studied.