Can I use Cerium and Ammonium Nitrate (NH₄)₂Ce(NO₃)₆ instead of using cerium nitrates Ce(NO3)3,6H2O for synthysis of perovskite ?
Yes, you can use Cerium and Ammonium Nitrate (NH₄)₂Ce(NO₃)₆ instead of using cerium nitrates Ce(NO3)3,6H2O for the synthesis of perovskite. Cerium (IV) ammonium nitrate ((NH 4) 2 Ce(NO 3) 6) is a one-electron oxidizing agent that is used for oxidative addition reactions of electrophilic radicals to alkenes, enabling intermolecular and intramolecular carbon-carbon and carbon-heteroatom bond formation. CAN also oxidizes secondary alcohols into ketones and benzylic alcohols into aldehydes.
The two compounds have different chemical properties and may require different reaction conditions. Therefore, it is essential to consult the literature and optimize the reaction conditions accordingly.
See:
Cerium Ammonium Nitrate - CAN (organic-chemistry.org)
Ceric ammonium nitrate - Wikipedia
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