The specific capacitance value of RuO2 nanoparticles from CV is comparatively low with GCD analysis because CV measures the total capacitance of the electrode material while GCD measures only the capacitance of the active material. The specific capacitance value obtained from CV is calculated by integrating the current over a range of voltage and dividing it by the scan rate and mass of active material. On the other hand, GCD measures the capacitance of only the active material by measuring the charge and discharge time of the electrode. The difference in specific capacitance values obtained from CV and GCD analysis can be attributed to various factors such as particle size, surface area, morphology, and porosity of RuO2 nanoparticles.