For CO2 measurements in our lab we use a gas analyser of the Horiba PG-350 series. Our experience with Horiba is good and they have portable analyzers too. OBS-ONE is one of their portable measuring systems.
Dear Susant kumar Padhi this is a very interesting discussion I think. Two years ago when our lab team was looking for a portable biogas analyzer we found that they are too expensive. At that time we decided to analyze our gas samples by GC-TCD (Ar). Now a number of papers have been published where a simple micro-controller based biogas analyzer have been developed using some open source materials, and their cost is low and efficiency is great. You can google arduino based methane and co2 analyzer which may be developed under 5000 INR.