I would think that under the right conditions you could probably image under an SEM to get a fairly good idea of the EPS presence. Obviously this would be dependent on the amount, but it could be a really quick method.
Bacterial biofilms consist of cells embedded in a self - produced matrix containing extracellular polymeric substances ( EPS ) such as polysaccharides, proteins, and DNA. Can be detected with electron microscopy images. There is rapid identification of bacterial biofilms using a Multichannel Nanosensor