If so, then what could be the possible reason? I am asking this question in context of a wastewater stream with COD ~ 1200 ppm and TDS close to 13000 ppm.
Dear Vit Mateju : Thanks for pointing out the vagueness of my question. I should have been more specific. My sample has inorganic TDS mostly in the form of sulphates of sodium and zinc.
Vit Mateju : I asked this question based on my laboratory experimental observation on using Fenton for COD reduction which also saw a moderate TDS reduction. Hence I thought of putting this question out in the community. Thanks for your comment.
Like what @nafees mentioned, TDS increases after Fenton, this is so since there would be degradation of larger contaminants to smaller ones. Also there is an addition of ferrous iron which contributes to TDS. The likely reason why your TDS actually increases is probably due to the coagulation phase post Fenton. I would assume that you adjusted the pH to precipitate out the iron. This act actually reduces the TDS due to the coagulation of compounds in wastewater with the ferric sludge. This was also observed in my thesis although not reported.