The rock has a high Zr concentration but low Zircon yield. Secondary zirconium sillicates like gitinsite, vlasovite, zektzerite are present, other than zircon. Is this zircon chemically seperable from the whole rock?
I suspect of dealing with a Zr concentration hosted by alkaline magmatic rocks. Any separation of a target mineral is first and foremost a question of the minerals which it is associated with. In pyroclastic rocks are certainly not only zircon and Zr silicates like vlasovite present. A more detailed information on the entire mineral assemblage is desireable. Otherwise chemical or mineralogical approaches taken are more or less a trial-and-error attempt the recovery grade of which cannot be determined.