You can make a paste of graphite with polyvinyl alcohol and drop-cast it. We have used this technique where we have drop-casted graphene, graphite, and CNTs. Check this paper for further reference:
Article Preparation of aluminium 6063-graphite surface composites by...
I think you can't deposit graphite alone by the drop-casting method. you need to use a binder. select the binder according to your required application.