Although I did not fully understand your question, charge transfer without involvement of any energy seems not possible. For any reaction to occur, we need to provide the activation energy (however small it may be). For intramolecular charge transfer in the excited state, the energy of the charge transfer state (final state) of the molecule must be lower than the locally excited state of the molecule. You may read the references: (i) Chem. Rev. 2003, 103, 3899−4031, (ii) Chem. Rev. 1997, 97, 173−205.
If your question is related to "adiabatic charge transfer' that requires zero activation energy, please see the link:
Thanks Dr Misra. Actually when we mix a donor and acceptor together it change the color in some cases. there is actually some charge transfer is occurring. right? that is without energy .. as we are not supplying any energy.