[About internal standard method using XRD for knowing the amount of zeolite in impurities.]

I want to know the amount of zeolite in impurities using internal standard method.

Alumina was selected as the standard sample、and made a calibration curve.

Usually,a calibration curve made from XRD is Straight line.

However my calibration curve is a beautiful curve(R^2=0.98)

What kind of problem can be considered?

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