Same metals i am trying to synthesis with same procedure and same condition but i am not able to achieve same X-Ray crystallites size using Scherrer relation or caglioti relation. In each and every literature survey i am getting diversified answers. Can anyone explain physics behind this problem or suggest me for the suitable literature i can follow preferably.
Thanks in advance.
Dear colleague Santhosh,
Have a nice time and good day.
The structural, optical and electrical properties of the final obtained alloy depend on the thermal literature, heating rate, cooling rate, coating rate or deposition rate, thermal aging, physical aging, homogeneity, container type.......etc.
the attached paper may help you how to treat XRD to calculate crystal size taking into account the instrumentation factor.
Dear colleague Santhosh,
Have a nice time and good day.
The structural, optical and electrical properties of the final obtained alloy depend on the thermal literature, heating rate, cooling rate, coating rate or deposition rate, thermal aging, physical aging, homogeneity, container type.......etc.
the attached paper may help you how to treat XRD to calculate crystal size taking into account the instrumentation factor.
Dear Eldenglawey,
Greetings to you!
Thank you for suggesting me a valuable paper.
Most often, the so-called grain size when determined with e.g. the Scherrer method are different of the microscopy observations. The reason is that those methods determine the size of the coherent diffracting domains (CDD), which are monocrystalline regions in the grains bounded by planar defects, what they can be, e.g. twins boundaries, dislocations walls, aso. Moreover, the X-ray method cannot accurately give a grain size distribution, rather the size of the larger CDD since the contribution of the smallest ones is hidden in the foot of the lines. As a result, the XRD grain size is generally smaller than the microscopy one.
Dear Gosset,
Greetings to you!
Thank you for your valuable suggestion.
Most of the time people comparing crystallite size obtained by XRD pattern. When compared two of my own data of same materials prepared by same synthesizing route under same environment condition i am getting same pattern. Both exhibiting the expected phase. But my question when i calculate crystallite size from the obtained data. The deflection was huge. Regarding this i gone through many literature survey i am getting different suggestions towards this issue like" some people suggesting heating rate affect and some people suggesting cooling rate will affect the size. So i am confused regarding this issue which one i will pick. I just want to know what will be the factors affecting crystallite size of a materials. I hope you understand my problem clearly.
Thanking You!
Dear Santhosh.
Only for atom-by-atom step synthesis you'll observed equal size.
For all other synthesis procedure, you'll observed average crystallite size.
All factors present in a first answer.I can add the next factors: defects of structure and the main plane of grown.
Dear Marat Zakirov,
Greetings to You!
Thank You for your valuable suggestion.
- Dear Dr. Santhosh Kumar M
I hope for all success.There are two attached papers may help you in your study
Good luck
Yours,
Ahmed Saeed Hassanien
Are u use Scherrer Formula (single peak), WH-Plot, WA-Method or WPPM? Did u subtract the instrument contribution? etc.For shortcut, post ur data together with the complete information of the optics configuration.
Dear Santhosh,
There are n number of parameters on which the crystallography of materials depends due to which you are observing the variation in crystallite size. In the very first answer, these are the obvious reasons due to which it happens.
I think pre-synthesis treatments also affect the formation of crystals. Like, If you are grinding the mixture of reactants before solid state heat treatment then the quality of grinding will affect the final micro-structure. There might be some reasons except this, you can think in this way also.
Sometimes, the position of your sample in furnace chamber might be different which may affect the structural properties. The different heating and cooling rates might be the reason of your problem.
Best of Luck! Hope you'll get rid of it soon....!
Dear Dr. Santhosh Kumar M
I hope for all success.There is an attached PPT may help you in your study
Good luck
Yours,
Ahmed Saeed Hassanien
Dear Ahmed Saeed Hassanien,
Thank you for the wonderful suggestions and attachments!
Dear Aayush,
Thanks for your valuable comments. Hope i might got some over all idea.
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