You can define multiple jobs.

For more detail, it is named as "6.6 Jobs with Multiple Steps" in the orca manual 4.2.1. I believe the same will work for ORCA 5

Here is an example:

# -----------------------------------------------------

! UKS LSD SVP grid5 NoFinalGrid TightSCF KeepInts

# -----------------------------------------------------

%eprnmr gtensor 1 end

* int 0 2

B 0 0 0 0 0 0

O 1 0 0 1.2049 0 0

*

# *************************************************

# ****** This starts the input for the next job *

# *************************************************

$new_job

# --------------------------------------------------

! BP86 SVP SmallPrint ReadInts NoKeepInts

# --------------------------------------------------

%eprnmr gtensor 1 end

* int 0 2

B 0 0 0 0 0 0

O 1 0 0 1.2049 0 0

*

To call the optimized geometry, you can use xyzfile flag.

Here is an example:

* xyzfile 0 2 .xyz