you can calculate it by computing bandgap of your lab prepared TiO2. E= hc/lamda.. Once u would have E, wavelength u will get.. Search google scholar any paper related to tittania and photocatalysis.
depends on your catalysts structure which is usually anatas or rutile you need a source to generate photons with the sufficient energy to excite the electrons which is in this case a source with a wavelength shorter than 385nm using this equation (1240/eV= wavelength (nm) ).
Note that various catalyst have different absorption properties based on variety of parameters like synthesis method, DOPANTS, or calcination temperature...