these following 2article would give you some helps
Template-free synthesis of MgO nanoparticles for effective photocatalytic applications - ScienceDirect https://www.sciencedirect.com/science/article/pii/S0032591013005937?via%3Dihub
Synthesis and applications of nano-MgO and composites for medicine, energy, and environmental remediation: a review | SpringerLink https://link.springer.com/article/10.1007%2Fs10311-021-01299-4
Dear Bakhtyar K. Aziz, I think your repoted value of Eg is much higher than the most common ones. The synthesis techniques and protocols highly influence the Eg values. Please check the following RG free access documents. My Regards