It will give one main band at ~66 kDa. You will probably also see bands for aggregates at multiples of 66 kDa. Impurities may also show up at various masses if it is not highly purified.
In general, one band should be observed at around 65 KDa for pure BSA. However, to make sure of the specificity of this band to BSA, you can transfer to nitrocellulose membrane, and expose to BSA antibody.