I want to analyze Graphene oxide by XRD and I want to use 0.02 degrees for step size. the rang of 2 theta is 5-80 degrees but I can not calculate the scan step time.
You are not calculating that but setting it. It all comes down to the instrumentation and required quality. What detector are you working with? For scintillation detectors we usually used 5-10 seconds per step to achieve reasonable measurement times.