A primary difference between photons would be:
Radio waves (3 kHz to 30 GHz) have lower frequencies of all types of EMR, and their photons carry less amount of energy. Interactions with matter depends on wavelength and energy density and create EM charges with absorption or emission.
Microwaves (30-300GHz) don’t bend (diffract) around hills or mountains, they don’t reflect back from the ionosphere (Micu, 20230). With higher frequency, microwaves penetrate more than RF waves transmit data over wireless networks, to communicate with satellites and spacecraft.