The CdSe band gap is 1.7 eV. why edep methods? why do not chemical bath deposition? Your TiO2 NTs are onto metal substrates ie there are still onto the original Ti plate?
You can think to deposit your sample with doped materials of low band gap. As for example: you can doped by other metal such as Cu (band gap of CuSe is 2.2 eV).