At present i am using LiCoO2+PVdF+Carbon Black for cathode and Graphite+PVdF as anode with polymer film (PEO/PVC + Tio2). I am doing charging and discharging but not getting good results. Capacity is very low.
By low vacuum sputtering or silver paste you may develop the temporary electrodes on your composite material or you may develop the film on a metallic substrate.