You can do XRD and see whether the main peak shifts, because this may indicate the Ag doing. XPS is more accurate that EDS, and it will be much helpful.
dear Asma Hayoune ; you can use you can use (a) Elemental analysis (EDS) of the silver doped TiO2 to show the presence of Ti and Ag species; (b) UV-Vis diffuse reflectance spectra (DRS) of Ag-doped TiO2, as in the reference ;
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