We have analyzed the relationships between water mineralization and electric conductivity (EC) of natural river waters in the Aral Sea Basin for last decade and have revealed that 1 mg of water salinity was equal to 1.41-1.52 µS/cm. The water quality standard for human consumptions around the world of 1 g/L in ASB basin will be reached when EC equal to about 1410-1520 µS/cm depending on the river basin. These findings will be published very soon in Book of abstracts of SETAC Orlando 2016 annual conference.
Look also at our article: Saving freshwater from salts. Science 351(6276):914-916 · February 2016.
Electrical conductivity and concentrations of total dissolved solids (TDS) are not related to each other one by one. But in dilute solutions (such as natural water) between these two factors are as follows:
TDS = 0.5 EC
The relationship between TDS and EC for any water sample due to its physical and chemical properties vary.
Conductivity values, EC, in mS/cm are converted to electrical resistivity values, rw, in Ohm.m by:
rw (Ohm.m) = 10* (1/ EC (mS/cm))
Subsequently, the values are corrected at a reference temperature of 20°C by
the expression (Sorensen and Glass, 1987):
rw20 = rw(Τ) [1 + α (T - T0)]
Where:
T = water temperature (°C)
α = temperature coefficient equal to 0.0177 1/°C (Beklemishev, 1963)
T0 = reference temperature equal 20°C
rw = water resistivity measured in field
rw 20 = water resistivity corrected at 20°C
For a reference temperature equal to 20°C, it is possible, for salinities below 10 g/l, to estimate the water salinity from water electrical resistivity using the relation:
C = 6 / rw20
Where C is the salt content (NaCl equivalent) in g/l
Water containing TDS concentrations below 1000 mg/litre is usually acceptable to
consumers, although acceptability may vary according to circumstances. However, the
presence of high levels of TDS in water may be objectionable to consumers owing to the resulting taste and to excessive scaling in water pipes, heaters, boilers, and household appliances. Water with extremely low concentrations of TDS may also be unacceptable to consumers because of its flat, insipid taste; it is also often corrosive to water-supply systems.
Electrical conductivity is a measure of water capacity to convey electric current. The most desirable limit of EC in drinking water is prescribed as 1,500 μmhos/cm (WHO, 2004). The EC of the groundwater is varying from 64.02 and 2199.57 μmhos/cm with an average value of 514 μmhos/cm. Higher EC in the present model of sand storage reservoir indicates the enrichment of salts in the two samples of water.
A quick way of estimating Salinity is to use a conductivity meter and read off the electrical conductivity (EC). The idea being that a salty solution, because it is full of charged particles will conduct electricity. Most conductivity meters give readings in micro Siemens per cm (µS/cm). Most fresh (drinking) water will have less than 100 µS/cm conductivity (EC).
Relation between conductivity (EC) and TDS: TDS is more precisely measured in the laboratory by evaporating a measured sample gently to dryness then calculating how much solids are left. Conductivity is usually given as µS/cm which measures the ability of the sample to conduct an electric current.
There is no exact but an approximate relationship between conductivity as µS/cm and TDS as ppm. In water with a higher proportion of sodium chloride to get TDS in ppm just multiply the EC µS/cm reading by 0.5. For most other water (like in hydroponics solutions) use a factor of 0.67 or 0.7 instead.
Relation between EC and chloride concentration: The electrical conductivity [EC] and chloride ion concentration values of ground water samples (in Mexico) were found to be related by the linear equation: [Cl-] = 4.928 EC (R> 0.94). [Reference: Cien. Inv. Agr. 39(1):229-239. 2012].
Hope the information is interesting and useful to you.
the literature about correlations for salinity evaluation by EC measurements is very abundant. However, you are asking for an assessment which includes TDS, i.e., total dissolved particles charged and not charged. You can obtain an evaluation of TDS by osmolarity measurements (Osmotic pressure, boiling temperature variation, melting temperature variation, the so called colligative properties of solutions). At the same time, you need information about the presence of charged solutes as chloride ions. You can consult a paper I published in 1980.