Well, after some researches I got that understanding:

we can measure the Effectiveness of the security system through analyzing its works without facing the system to any threats or attacks. And after the analysis we gonna be able to know whether the system effective or not.

Whereas,

In order to meassure the functionality of the security system, it should apply under an attack scenarios and analysis its work. And after the analysis we can know how much the functionality of the security system.

Any better illustration, and thanks in advance (:

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