There are plenty NLO applications for nanoparticles; photonic crystal, optical diode, optical limiters, optical switches etc. to name a few.
This book should give you a comprehensive overview of NLO applications of nanoparticles > http://www.tmhshop.com/a-textbook-of-nanoscience-and-nanotechnology
I do not know of any commercial products that uses nanotechnology for NLO applications. These are still in the development stage. One potential application that is close to commercial production is probably two photon fluorescent QDs for medical imaging. There are plenty of optical products (commercial) that uses nanotechnology.