1. If you want to check coating performance with pin material, then it is not going to be the solution. Because the coating compatibility can only be understood after coating the pin not disc.
Yes, it is no problem to change.Just do remind that the residual stress built u on flat surface and on curve surface will be different. Thus it might affecting the wear amount result.
While evaluating the tribological performance of the coating, the disc is coated and standard balls are used as the counter body. Instead of balls, pins can also be used. But the availability of standard balls (of WC, alumina, silicon nitride etc.) is better as compared to pins.