Thank you for your question. I am a sedimentology and mineralogy geologist. Separating chemical compounds requires a purely chemical action. I sent some links that may be useful.
Article Foam Separation of Cyanide Complexed by Iron
Both ferrocyanides and ferricyanides will disassociate in the presence of ultraviolet light, this is an equilibrium reaction.
In solution, if the pH of the solution is raised to around 11 then the ferric ions will form insoluble ferric hydroxide, thus driving the equilibrium to completion with formation of ferric hydroxides and soluble cyanide complexes.
Ferrocyanides will slowly form ferri complexes by oxidation from dissolved oxygen in the water thus forming ferric hydroxides and soluble cyanide complexes.
UV can be supplied by natural sunlight or by artificial uv sources.
As uv light is a poor penetrant of water the reaction can be sped up by agitation of the liquid to bring the ferro/ferricyanide complexes to the liquid surface where they are readily reacted with any uv rays.
I made electrolyte solution of potassium ferricyanide/ferricyanide in pbs and it keeps degrading and decoloring in few days. I don't know why. I wish it can help you