In the Raman spectra of doped SrTiO3, a strong peak appears at 151.24cm-1 who intensity increased with doping. However, there is no such peak for pure SrTiO3 ceramics. The peak slightly shifted from 151.24cm-1 to 144.46cm-1 with further doping. Can anyone know the mode of this peak like TO2,TO3 etc. Secondly why the peak shifted with doping?