Suppose we have a metal core surrounded by organic ligands. In that case, can a ligand act as/can be termed as a shell or is there any obvious difference between the two?
It's not hard to differentiate between ligands and inorganic/organic metal shell by looking at the TEM images, but I am just not sure about the real concept. Is something to do with the difference between the bonding of ligands with the metal atom/ core and the bonding of a organic/inorganic shell with the core?
Ligands and shell are two very different things, with ligands you can perform a functionalization between two incompatible materials, it's not a shell because don't act like as a physical barrier, it's only an attachment with others particles. Usually shell growth in all the nanoparticle's surface.