Williamson-Hall plot is related with XRD. The basic calculation for the plot can be done using the XRD data. It gives the crystallite size and the strain. Because of the strain involved the calculated particle size is most of the times larger then the size calculated from the XRD spectra. Plot a graph between Sin(theta)/lambda and beta*cos(theta)/lambda and fit a linear curve using origin or any other similar software. The slope of the fitted line gives you the crystallite size and the intercept gives you the strain. Here beta is the fwhm and all values including theta should be converted to radians before doing the calculations.

Regards

If you have any other doubts and if I am able to clarify u can revert back.

The original paper and the same number of examples can be found on ResearchGate:

Article X-Ray Line Broadening from Filed Aluminum and Wolfram

Article Microstructure study on BN nanocomposites using XRD and HRTEM

Dear Haarindra

In the "Williamson-Hall" following equation is used:

βCosθ= Kλ/D+C.e.Sinθ

Where β is the full width of the Bragg peak at half maximum (FWHM), θ is peak angle, D is mean crystallite size, e is strain and K~1. by comparing this to the standard equation for a straight line (m = slope; c = intercept)

y = mx + c

The slope of the plot βCosθ vs Sinθ yields (C.e) strain and the intercept gives Kλ/D.

In addition, you can use "Cauchy-Gaussian" equation for measuring crystallite size and strain

Can apply this method on all thin films or just on powder?

Dear Sir, In a book there mentioned this

Williamson-hall plot the approximate formulae for size broadening, βL, and strain broadening, βe , vary quite differently with respect to Bragg angle, θ:

βL =KλL cosθ βe =Cε tanθ

One contribution varies as 1/cosθ and the other as tanθ. If both contributions are present then their combined effect should be determined by convolution. The simplification of Williamson and Hall is to assume the convolution is either a simple sum or sum of squares (see previous discussion on Sources of Peak Broadening within this section). Using the former of these then we get:

βtot = βe + βL = Cε tanθ +KλL cosθ

If we multiply this equation by cosθ we get:

βtot cosθ = Cε sinθ +KλL

and comparing this to the standard equation for a straight line (m = slope; c = intercept)

y = mx + c

we see that by plotting βtotcosθ versus sinθ we obtain the strain component from the slope (Cε) and the size component from the intercept (Kλ/L). Such a plot is known as a Williamson-Hall plot and is illustrated schematically below (note that this plot could alternatively be expressed in reciprocal space parameters, β* versus d*):

http://prism.mit.edu/xray/oldsite/5a%20Estimating%20Crystallite%20Size%20Using%20XRD.pdf

Article Williamson-Hall analysis in estimation of lattice strain in ...

For Scherrer equation, crystallite size was calculated based on the measurement of a(hkl) peak using the following equation:

L =Kλ / Bsize cos θ

where L is crystallite size, K is a dimensionless shape factor (0.9), Bsize is line broadening at half of the maximum intensity (FWHM) in radian, λ is the X-ray wavelength for example for Cu Kα radiation (1.5406 Å) and θ is Bragg angle in degree.

Meanwhile, Williamson–Hall plot was used to estimate the crystallite size and lattice strain of the samples using the following formalism:

Btot = Bstrain + Bsize = 4Cε tanθ + Kλ/ L cosθ

where Cɛ is the lattice strain, Βsize is the particle size broadening, Βstrain is the strain broadening, L is the crystallite size, K is a dimensionless shape factor (0.9), λ is the X-ray wavelength for Cu Kα radiation (1.5406 Å) and θ is Bragg angle in degree.

Then Eq. 2 is multiplied by cosθ to yield:

Btot (3) cosθ = 4Cε sinθ + Kλ/L

Hence, by plotting the graph of Βtot cosθ against 4 sinθ, the lattice strain, Cɛ of the sample can be obtained from the slope (gradient) while the crystallite size can be estimated from the intercept (Kλ/L).

Williamson–Hall’s formula determines the particle size of the NPs, as shown below

β cosθ= 0.89λ/d+ 4εsinθ . where, λ, β, θ, ε and d ascertain the wavelength of Cu Kα radiation, the FWHM, the Bragg angle, the strain

and the mean size of the particles respectively. The expression 4sinθ along the x-axis and cosθ along the y-axis are usually plotted for NPs. According to the linear fit of the data, the crystalline size was estimated from the y-intercept

Williamson–Hall’s formula determines the particle size of the NPs, as shown below β cosθ= 0.89λ/d+ 4εsinθ . where, λ, β, θ, ε and d ascertain the wavelength of Cu Kα radiation, the FWHM, the Bragg angle, the strain and the mean size of the particles respectively. The expression 4sinθ along the x-axis and cosθ along the y-axis are usually plotted for NPs. According to the linear fit of the data, the crystalline size was estimated from the y-intercept

Mohsen Mehrabi

The Williamson-Hall method does not determine particle size of nanoparticles.

Haarindra Prasad

see this document for guidance.

kind regards

Santanu

I want to get the components of the compliance matrix, Sij (value of S11, S12, S44) for copper (Cu) in order to calculate Young’s Modulus (Ehkl) of a specific crystallographic plane. Are there any international standard data/table to obtain these values? If so, please provide that with your valuable feedback.

Haarindra Prasad The Williamson-Hall Plot. W-H plot is used to calculate the crystallite size and microstrain from complex XRD data. That's when both the crystallite size and microstrain vary as a function of the Bragg's angle, we can only calculate these parameters from XRD data using W-H plot. I have provided the practice file (Origin file) as well as the calculation file (Excel file) in the video description. Thanks

https://youtu.be/ipX3iUJ5VcU

W-H plot helps to measure the crystallite size and micro-strain produced in the crystal structure. It supports the structural analysis and calculation made using Debye-scherrer equation.

Please find the article for examples:

Article Structural, photoluminescence, antibacterial and biocompatib...