I need a material that works like a hydrophobic agent and should be low cost and effective as well as trimethylethoxysilane or something like that. I need an agent that isn't harmful for nature and humans.
Please be more specific: do you want to coat a material with it, or is it for another purpose. The most environment-friendly hydrophobic agents are paraffines or waxes.
You can get hydrophopic material by coating it with a polymer. There is a lot of polymers (dissolving in water) and even biodegradable such as PVA that you can use to coat, but you must take in your concern the low concentration of the polymer solution to get high quality coating layer.