Hello,

I hope this message finds you well. I have just started to learn gaussian software. While running NLO calculations I used the keyword:

#p b3lyp/6-31g(d,p) geom=connectivity gfinput polar=(DCSHG, Cubic) CPHF=RdFreq 

Later I came to know the common keyword used for NLO is:

# b3lyp 6-31G(d,p) Polar=(DCSHG,Cubic) CPHF=RdFreq.

Which is the most apt set of keyowrds. And what is the difference between # and #p.

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