I hope this method can applied for your problem, but i don't make sure, where in order to eliminate unwanted phases that form in my compound during the crystallization process KCN chemical treatment was applied to the samples, this procedure can be concluded the following steps:
1- Solution of KCN at 10% w/w prepared.
2- The samples were sequentially submitted to the KCN bath.
3- The samples were submitted to solution of alcohol/deionized water at 50% vol/vol.
4- finally,The samples were submitted to solution of deionized water.
Each step had a duration of 2 min.
Finally, all samples were dried with a N2 gas flux.
The copper(II) oxide layer formed over metallic copper can be dissolved with hot dilute acetic acid. However, some attack to aluminium, not strong and seemingly acceptable for the intended application, is to be expected. Such attack would be partially due to galvanic corrosion, since both metals would be in contact.
Concentrated hydrochloric acid can remove CuO easily. Diluted HCl is OK, too. The cooper won't react with acid.
You may also try boiling the specimen in H2C2O4 and K2C2O4(1:2) solution in a water bath, cause Cu(II) could react with C2O42- forming coordiation compounds.