How does the morphology of impurity affects the dielectric properties. The impurity phase is Hematite so can anyone suggest or refer some literature regarding this.
It is well known that impurities have dominant effect on the conductivity of
semiconductors and therefore on the imaginary part of permittivity (sigma/Omega/eps0 term in the imeginary part of permittivity). In dielectrics, or in wide band-gap semiconductors impurities have relatively small influence on the dielectric properties
up to microwave frequencies (compare e.g. dielectric properties of sapphire and ruby)
Doping of a semiconductor introduces defect levels within the band gap of the semiconductor and this alters the properties of the gap. If the VB and the CB are considered as 2 conductors then the introduction of the impurities alters the dielectric?
Doping results in change in band gap, polarization (particularly interfacial), conductivity or resistivity. This altogether can increase or decrease the dielectric constant and dielectric loss.
the Hematite (impurity phase) might give rise to a new inductive impedance component scaled with the impurity phase density. Related and useful infos can be found in : Negative capacitance (impedance of the inductive type) of silicon... https://link.springer.com/article/10.1134/S1063782606070128